Binder-Free Hybrid Titanium-Niobium Oxide/Carbon Nanofiber Mats for Lithium-Ion Battery Electrodes.

Title Binder-Free Hybrid Titanium-Niobium Oxide/Carbon Nanofiber Mats for Lithium-Ion Battery Electrodes.
Authors A. Tolosa; S. Fleischmann; I. Grobelsek; A. Quade; E. Lim; V. Presser
Journal ChemSusChem
DOI 10.1002/cssc.201701927
Abstract

Free-standing, binder-free, titanium-niobium oxide/carbon hybrid nanofibers are prepared for Li-ion battery applications. A one-pot synthesis offers a significant reduction of processing steps and avoids the use of environmentally unfriendly binder materials, making the approach highly sustainable. Tetragonal Nb2 O5 /C and monoclinic Ti2 Nb10 O29 /C hybrid nanofibers synthesized at 1000?°C displayed the highest electrochemical performance, with capacity values of 243 and 267?mAh?g-1 , respectively, normalized to the electrode mass. At 5?A?g-1 , the Nb2 O5 /C and Ti2 Nb10 O29 /C hybrid fibers maintained 78?% and 53?% of the initial capacity, respectively. The higher rate performance and stability of tetragonal Nb2 O5 compared to that of monoclinic Ti2 Nb10 O29 is related to the low energy barriers for Li+ transport in its crystal structure, with no phase transformation. The improved rate performance resulted from the excellent charge propagation in the continuous nanofiber network.

Citation A. Tolosa; S. Fleischmann; I. Grobelsek; A. Quade; E. Lim; V. Presser.Binder-Free Hybrid Titanium-Niobium Oxide/Carbon Nanofiber Mats for Lithium-Ion Battery Electrodes.. ChemSusChem. 2018;11(1):159170. doi:10.1002/cssc.201701927

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Niobium

See more Niobium products. Niobium (atomic symbol: Nb, atomic number: 41) is a Block D, Group 5, Period 5 element with an atomic weight of 92.90638. Niobium Bohr ModelThe number of electrons in each of niobium's shells is 2, 8, 18, 12, 1 and its electron configuration is [Kr] 4d4 5s1. The niobium atom has a radius of 146 pm and a Van der Waals radius of 207 pm. Niobium was discovered by Charles Hatchett in 1801 and first isolated by Christian Wilhelm Blomstrand in 1864. In its elemental form, niobium has a gray metallic appearance. Niobium has the largest magnetic penetration depth of any element and is one of three elemental type-II superconductors (Elemental Niobiumalong with vanadium and technetium). Niobium is found in the minerals pyrochlore, its main commercial source, and columbite. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus.

Titanium

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

Lithium

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