Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets.

Title Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets.
Authors D.A. Rotsch; A. Brown; J.A. Nolen; T. Brossard; W.F. Henning; S.D. Chemerisov; R.G. Gromov; J. Greene
Journal Appl Radiat Isot
DOI 10.1016/j.apradiso.2017.11.007
Abstract

The photonuclear production of no-carrier-added (NCA)Sc from solidTiOand the subsequent chemical processing and purification have been developed. Scandium-47 was produced by theTi(?,p)Sc reaction with Bremsstrahlung photons produced from the braking of electrons in a high-Z (W or Ta) convertor. Production yields were simulated with the PHITS code (Particle and Heavy Ion Transport-code System) and compared to experimental results. Irradiated TiOtargets were dissolved in fuming HSOin the presence of NaSOandSc was purified using the commercially available Eichrom DGA resin. TypicalSc recovery yields were >90% with excellent specific activity for small batches (<185 MBq batches).

Citation D.A. Rotsch; A. Brown; J.A. Nolen; T. Brossard; W.F. Henning; S.D. Chemerisov; R.G. Gromov; J. Greene.Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets.. Appl Radiat Isot. 2018;131:7782. doi:10.1016/j.apradiso.2017.11.007

Related Elements

Scandium

See more Scandium products. Scandium (atomic symbol: Sc, atomic number: 21) is a Block D, Group 3, Period 4 element with an atomic weight of 44.955912. The number of electrons in each of Scandium's shells is [2, 8, 9, 2] and its electron configuration is [Ar] 3d1 4s2. Scandium Bohr Model The scandium atom has a radius of 162 pm and a Van der Waals radius of 216 pm.Scandium was predicted by Dmitri Mendeleev in 1871 and actually discovered and isolated by Lars Nilson in 1879. One of the transition metals, scandium has a silvery-white appearance in its elemental form which oxidizes to yellow or pinkish upon contact with air. Elemental ScandiumIt is occasionally included in the classification of the rare earth elements. Scandium is found in concentrated amounts in the minerals euxenite, gadolinite and thortveitite however, due to the difficulties in the preparation of metallic scandium, global trade of the pure metal is very limited. The origin of the name scandium comes from the Latin word 'scandia' meaning Scandinavia.

Titanium

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

Related Forms & Applications