American Elements
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
Ir(C8H12)(C5H5N)[P(C6H11)3]PF6
64536-78-3
Product
Product Code
Order or Specifications
99% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-02
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99.5% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-025
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99.9% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-03
 Contact American Elements
99.95% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-035
 Contact American Elements
99.99% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-04
 Contact American Elements
99.999% 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
IR-OM5-05
 Contact American Elements
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Iridium is a Block D, Group 9, Period 6 element. The electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs.

Formula CAS No. Appearance Molecular Weight
Ir(C8H12)(C5H5N)[P(C6H11)3]PF6 64536-78-3 804.89
PRODUCT CATALOG
Iridium Products
Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Iridium

  • Chiral or not chiral? A case study of the hexanuclear metalloprisms [Cp*(6)M(6)(micro(3)-tpt-kappaN)(2)(micro-C(2)O(4)-kappaO)(3)](6+) (M = Rh, Ir, tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine). Dalton Trans. 2007 Oct 21;(39):4457-63. Epub 2007 Sep 11.

  • New approach to radiation burn treatment by dosimetry-guided surgery combined with autologous mesenchymal stem cell therapy. Regen Med. 2007 Sep;2(5):785-794.

  • Luminescent Iridium Phenanthroline Crown Ether Complex for the Detection of Silver(I) Ions in Aqueous Media. Inorg Chem. 2007 Sep 29; [Epub ahead of print]

  • Evidence for an extraterrestrial impact 12,900 years ago that contributed to the megafaunal extinctions and the Younger Dryas cooling. Proc Natl Acad Sci U S A. 2007 Sep 27; [Epub ahead of print]

  • Carbonyl Allylation in the Absence of Preformed Allyl Metal Reagents: Reverse Prenylation via Iridium-Catalyzed Hydrogenative Coupling of Dimethylallene. J Am Chem Soc. 2007 Sep 27; [Epub ahead of print]

  • Iridium-Catalyzed Reduction of Alkyl Halides by Triethylsilane. J Am Chem Soc. 2007 Sep 27; [Epub ahead of print]

  • Synthesis and characterisation of high-nuclearity osmium-silver mixed-metal clusters. Chem Commun (Camb). 2007 Oct 14;(38):3924-6. Epub 2007 Aug 23.

  • Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins. Angew Chem Int Ed Engl. 2007 Sep 21; [Epub ahead of print] No abstract available.

  • Catalyzed Dehydrogenation of Ammonia-Borane by Iridium Dihydrogen Pincer Complex Differs from Ethane Dehydrogenation. Angew Chem Int Ed Engl. 2007 Sep 20; [Epub ahead of print] No abstract available.

  • The Role of Substituents on Functionalized 1,10-Phenanthroline in Controlling the Emission Properties of Cationic Iridium(III) Complexes of Interest for Electroluminescent Devices. Inorg Chem. 2007 Sep 21; [Epub ahead of print]

  • Is the Treatment of Keloid Scars Still a Challenge in 2006?
    Ann Plast Surg. 2007 Feb;58(2):186-192.

  • Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding.
    J Am Chem Soc. 2007 Jan 31;129(4):853-66.

  • Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes.
    J Am Chem Soc. 2007 Jan 31;129(4):776-7.

  • Iridium(I)-catalyzed regio- and enantioselective decarboxylative allylic amidation of substituted allyl benzyl imidodicarbonates.
    J Am Chem Soc. 2007 Jan 31;129(4):774-5.

  • Design and optimization of molecular nanovalves based on redox-switchable bistable rotaxanes.
    J Am Chem Soc. 2007 Jan 24;129(3):626-34.

  • Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers.
    J Am Chem Soc. 2007 Jan 24;129(3):588-600.

  • High Enantioselectivity Is Induced by a Single Monodentate Phosphoramidite Ligand in Iridium-Catalyzed Asymmetric Hydrogenation.
    Angew Chem Int Ed Engl. 2007 Jan 16; [Epub ahead of print] No abstract available.

  • Hydrogen-Atom Transfer in Open-Shell Organometallic Chemistry: The Reactivity of Rh(II)(cod) and Ir(II)(cod) Radicals.
    Chemistry. 2007 Jan 12; [Epub ahead of print]

  • Iridium-Catalyzed C-C Bond Forming Hydrogenation: Direct Regioselective Reductive Coupling of Alkyl-Substituted Alkynes to Activated Ketones.
    J Am Chem Soc. 2007 Jan 17;129(2):280-281.

  • Unresectable hilar cholangiocarcinoma: multimodality approach with percutaneous treatment associated with radiotherapy and chemotherapy.
    In Vivo. 2006 Nov-Dec;20(6A):757-60.

 

 

 

 

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