On the use of solid-state (45)Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts.

Title On the use of solid-state (45)Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts.
Authors T. Vancompernolle; X. Trivelli; L. Delevoye; F. Pourpoint; R.M. Gauvin
Journal Dalton Trans
DOI 10.1039/c7dt02415k
Abstract

Tris- and tetra-coordinated scandium amides were grafted onto silica and probed as catalysts for alkyne dimerization. (45)Sc NMR was carried out, providing information about the metal coordination sphere. The increasing number of coordinated ligands was correlated with decreased catalytic activity.

Citation T. Vancompernolle; X. Trivelli; L. Delevoye; F. Pourpoint; R.M. Gauvin.On the use of solid-state (45)Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts.. Dalton Trans. 2017;46(39):1317613179. doi:10.1039/c7dt02415k

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