American Elements

Palladium Acetylacetonate
Pd(CH3COCHCOCH3)2
14024-61-4
Product
Product Code
Order or Specifications
99% Palladium Acetylacetonate
PD-ACAC-02
 Contact American Elements
99.9% Palladium Acetylacetonate
PD-ACAC-03
 Contact American Elements
99.99% Palladium Acetylacetonate
PD-ACAC-04
 Contact American Elements
99.999% Palladium Acetylacetonate
PD-ACAC-05
 Contact American Elements
Palladium Acetylacetonate is a Palladium source that is soluble in organic solvents. The acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring. Because of this property, Palladium Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Palladium Acetylacetonate is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Palladium include jewelry, dentistry, watch making, and in making surgical instruments and electrical contacts. Additional technical, research and safety (MSDS) information is available.

Palladium is a Block D, Group 10, Period 5 element. The electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the platinum group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other platinum group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Pd(CH3COCHCOCH3)2 14024-61-4 Yellow 304.623   205°C   Soluble in organic solvents  
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Palladium

  • Bulky Chiral Carbene Ligands and Their Application in the Palladium-Catalyzed Asymmetric Intramolecular alpha-Arylation of Amides. Angew Chem Int Ed Engl. 2007 Oct 2; [Epub ahead of print] No abstract available.

  • Consecutive palladium-catalyzed Hiyama-Heck reactions in aqueous media under ligand-free conditions. Chem Commun (Camb). 2007 Oct 21;(39):4056-8. Epub 2007 Jul 25.

  • Efficient and Practical Synthesis of 4(5)-Aryl-1H-imidazoles and 2,4(5)-Diaryl-1H-imidazoles via Highly Selective Palladium-Catalyzed Arylation Reactions. J Org Chem. 2007 Oct 2; [Epub ahead of print]

  • Zirconocene-Mediated Highly Regio- and Stereoselective Synthesis of Multisubstituted Olefins Starting from 1-Alkynylboronates. J Am Chem Soc. 2007 Oct 2; [Epub ahead of print]

  • Efficient and Convenient Heterogeneous Palladium-Catalyzed Regioselective Deuteration at the Benzylic Position. Chemistry. 2007 Oct 1; [Epub ahead of print]

  • Microwave-Assisted Palladium-Catalyzed Direct Arylation of 1,4-Disubstituted 1,2,3-Triazoles with Aryl Chlorides. Chem Asian J. 2007 Oct 1; [Epub ahead of print]

  • Dinuclear palladium(ii) complexes with bridging amidate ligands. Dalton Trans. 2007 Oct 21;(39):4399-404. Epub 2007 Sep 13.

  • "Oxidationless" Promotion of Rapid Palladium Redispersion by Oxygen during Redox CO/(NO+O(2)) Cycling. Angew Chem Int Ed Engl. 2007 Oct 1; [Epub ahead of print] No abstract available.

  • Synthesis of Spirocyclic C-Arylglycosides and -Ribosides by Ruthenium-Catalyzed Cycloaddition. Chem Asian J. 2007 Sep 28; [Epub ahead of print]

  • The Electronic Structure of the Tris(ethylene) Complexes [M(C(2)H(4))(3)] (M=Ni, Pd, and Pt): A Combined Experimental and Theoretical Study. Chemistry. 2007 Sep 28; [Epub ahead of print] <Br>

  • Growth of colloidal gold nanostars and nanowires induced by palladium doping.
    Langmuir. 2007 Jan 30;23(3):1496-9.

  • Synthesis of Iron Nanoparticles via Chemical Reduction with Palladium Ion Seeds.
    Langmuir. 2007 Jan 30;23(3):1419-26.

  • Dosimetric parameters as predictive factors for biochemical control in patients with higher risk prostate cancer treated with Pd-103 and supplemental beam radiation.
    Int J Radiat Oncol Biol Phys. 2007 Feb 1;67(2):342-6.

  • Structural study of four complexes of the M-N(2)S(2) type derived from diethylphenylazothioformamide and the metals palladium, platinum, copper and nickel.
    Acta Crystallogr B. 2007 Feb;63(Pt 1):151-6. Epub 2007 Jan 15.

  • Structure determination of di-mu-hydroxo-bis[(2-(2-pyridyl)phenyl-kappa(2)N,C(1))palladium(II)] by X-ray powder diffractometry.
    Acta Crystallogr B. 2007 Feb;63(Pt 1):75-80. Epub 2007 Jan 15.

  • Electric field-induced modification of magnetism in thin-film ferromagnets.
    Science. 2007 Jan 19;315(5810):349-51.

  • Facile Aqueous-Phase Synthesis of Uniform Palladium Nanoparticles of Various Shapes and Sizes.
    Small. 2007 Jan 18; [Epub ahead of print] No abstract available.

  • Intermolecular chirality transfer from silicon to carbon: interrogation of the two-silicon cycle for pd-catalyzed hydrosilylation by stereoisotopochemical crossover.
    J Am Chem Soc. 2007 Jan 24;129(3):502-3.

  • Low-Temperature Heck Reactions of Axially Chiral o-Iodoacrylanilides Occur with Chirality Transfer: Implications for Catalytic Asymmetric Heck Reactions.
    J Am Chem Soc. 2007 Jan 24;129(3):494-5.

  • Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R=Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran.
    Dalton Trans. 2006 Dec 21;(47):5593-604. Epub 2006 Oct 10.

 

 

 

 

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