American Elements
Rhodium Chloride
RhCl3·xH2O
Product
Product Code
Order or Specifications
99% Rhodium Chloride
RH-CL-01
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99.9% Rhodium Chloride
RH-CL-03
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99.99% Rhodium Chloride
RH-CL-04
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99.999% Rhodium Chloride
RH-CL-05
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Rhodium Chloride is an excellent water soluble crystalline Rhodium source for uses compatible with chlorides. Chloride compounds can conduct electricity when fused or dissolved in water. Chloride materials can be decomposed by electrolysis to chlorine gas and the metal. They are formed through various chlorination processes whereby at least one chlorine anion (Cl-) is covalently bonded to the relevant metal or cation. Ultra high purity and proprietary formulations can be prepared. The chloride ion controls fluid equilibrium and pH levels in metabolic systems. Rhodium Chloride is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Rhodium Chloride Solution. Additional technical, research and safety (MSDS) information is available.

Rhodium is a Block D, Group 9, Period 5 element. The electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm.

Formula CAS No. Appearance Molecular Weight
RhCl3·xH2O 20765-98-4 Brown Powder 209.26
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Rhodium

  • Competitive O-H and C-H oxidative addition of CH(3)OH to rhodium(ii) porphyrins. Chem Commun (Camb). 2007 Oct 21;(39):4024-5. Epub 2007 Aug 29.

  • Enantioselective catalysis with tropos ligands in chiral ionic liquids. Chem Commun (Camb). 2007 Oct 21;(39):4012-4. Epub 2007 Sep 10.

  • Effective Modulation of the Donor Properties of N-Heterocyclic Carbene Ligands by "Through-Space" Communication within a Planar Chiral Scaffold. J Am Chem Soc. 2007 Oct 2; [Epub ahead of print]

  • Solvent-Dependent Interconversions between Rh(I), Rh(II), and Rh(III) Complexes of an Aryl-Monophosphine Ligand. Chemistry. 2007 Sep 28; [Epub ahead of print]

  • Molecular beam optical Stark study of the [18.1] (2)Pi(12)-X (4)Sigma(12) (-) band system of rhodium monosulfide. J Chem Phys. 2007 Sep 28;127(12):124311.

  • Mo/Rh Carboxylate: Heterometallic Compound Built of Homometallic Paddlewheel Units. Inorg Chem. 2007 Sep 28; [Epub ahead of print]

  • Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation. Chem Commun (Camb). 2007 Oct 14;(38):3903-5. Epub 2007 Aug 15.

  • Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I). Dalton Trans. 2007 Aug 14;(30):3224-6. Epub 2007 Jun 25.

  • delta-Sultone Formation Through Rh-Catalyzed C-H Insertion. Org Lett. 2007 Sep 21; [Epub ahead of print]

  • The estimation of the bioavailabilities of platinum, palladium and rhodium in vehicle exhaust catalysts and road dusts using a physiologically based extraction test. Sci Total Environ. 2007 Sep 18; [Epub ahead of print]

  • Anomalous Reaction of Rh(2)(OAc)(4)-Generated Transient Carbonyl Ylides: Chemoselective Synthesis of Epoxy-Bridged Tetrahydropyranone, Oxepanone, Oxocinone, and Oxoninone Ring Systems.
    J Org Chem. 2007 Jan 23; [Epub ahead of print]

  • De Novo Synthesis of Troc-Protected Amines: Intermolecular Rhodium-Catalyzed C-H Amination with N-Tosyloxycarbamates.
    Org Lett. 2007 Jan 23; [Epub ahead of print]

  • An Unexpected Pathway for the Catalytic Oxidation of Methylidyne on Rh{111} as a Route to Syngas.
    J Am Chem Soc. 2007 Jan 23; [Epub ahead of print]

  • Initial clinical experience with contrast-enhanced digital breast tomosynthesis.
    Acad Radiol. 2007 Feb;14(2):229-38.

  • Reverse micelle synthesis of rhodium nanoparticles.
    J Colloid Interface Sci. 2006 Dec 28; [Epub ahead of print]

  • Synthesis of Potent Bicyclic Bisarylimidazole c-Jun N-Terminal Kinase Inhibitors by Catalytic C-H Bond Activation.
    J Am Chem Soc. 2007 Jan 24;129(3):490-1.

  • Hydrogen-Atom Transfer in Open-Shell Organometallic Chemistry: The Reactivity of Rh(II)(cod) and Ir(II)(cod) Radicals.
    Chemistry. 2007 Jan 12; [Epub ahead of print]

  • Rhodium(I)-Catalyzed Allenic Carbocyclization Reaction Affording delta- and epsilon-Lactams.
    Org Lett. 2007 Jan 18;9(2):347-9.

  • Separation preconcentration method for platinum and rhodium from environmental samples using a chelating resin.
    Ann Chim. 2006 Nov-Dec;96(11-12):707-14.

  • Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds.
    Dalton Trans. 2007 Jan 28;(4):407-9. Epub 2006 Dec 13.

 

 

 

 

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