American Elements
Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
C16H24Cl2Rh2
12092-47-6
Product
Product Code
Order or Specifications
99% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-02
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99.5% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-025
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99.9% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-03
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99.95% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-035
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99.99% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-04
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99.999% Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
RH-OM36-05
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Chloro(1,5-cyclooctadiene)rhodium(I) Dimer is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™. Additional technical, research and safety information is available.

Rhodium is a Block D, Group 9, Period 5 element. The electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm.

Formula CAS No. Appearance Molecular Weight
C16H24Cl2Rh2
 12092-47-6 493.08
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Rhodium

  • Competitive O-H and C-H oxidative addition of CH(3)OH to rhodium(ii) porphyrins. Chem Commun (Camb). 2007 Oct 21;(39):4024-5. Epub 2007 Aug 29.

  • Enantioselective catalysis with tropos ligands in chiral ionic liquids. Chem Commun (Camb). 2007 Oct 21;(39):4012-4. Epub 2007 Sep 10.

  • Effective Modulation of the Donor Properties of N-Heterocyclic Carbene Ligands by "Through-Space" Communication within a Planar Chiral Scaffold. J Am Chem Soc. 2007 Oct 2; [Epub ahead of print]

  • Solvent-Dependent Interconversions between Rh(I), Rh(II), and Rh(III) Complexes of an Aryl-Monophosphine Ligand. Chemistry. 2007 Sep 28; [Epub ahead of print]

  • Molecular beam optical Stark study of the [18.1] (2)Pi(12)-X (4)Sigma(12) (-) band system of rhodium monosulfide. J Chem Phys. 2007 Sep 28;127(12):124311.

  • Mo/Rh Carboxylate: Heterometallic Compound Built of Homometallic Paddlewheel Units. Inorg Chem. 2007 Sep 28; [Epub ahead of print]

  • Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation. Chem Commun (Camb). 2007 Oct 14;(38):3903-5. Epub 2007 Aug 15.

  • Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I). Dalton Trans. 2007 Aug 14;(30):3224-6. Epub 2007 Jun 25.

  • delta-Sultone Formation Through Rh-Catalyzed C-H Insertion. Org Lett. 2007 Sep 21; [Epub ahead of print]

  • The estimation of the bioavailabilities of platinum, palladium and rhodium in vehicle exhaust catalysts and road dusts using a physiologically based extraction test. Sci Total Environ. 2007 Sep 18; [Epub ahead of print]

  • Anomalous Reaction of Rh(2)(OAc)(4)-Generated Transient Carbonyl Ylides: Chemoselective Synthesis of Epoxy-Bridged Tetrahydropyranone, Oxepanone, Oxocinone, and Oxoninone Ring Systems.
    J Org Chem. 2007 Jan 23; [Epub ahead of print]

  • De Novo Synthesis of Troc-Protected Amines: Intermolecular Rhodium-Catalyzed C-H Amination with N-Tosyloxycarbamates.
    Org Lett. 2007 Jan 23; [Epub ahead of print]

  • An Unexpected Pathway for the Catalytic Oxidation of Methylidyne on Rh{111} as a Route to Syngas.
    J Am Chem Soc. 2007 Jan 23; [Epub ahead of print]

  • Initial clinical experience with contrast-enhanced digital breast tomosynthesis.
    Acad Radiol. 2007 Feb;14(2):229-38.

  • Reverse micelle synthesis of rhodium nanoparticles.
    J Colloid Interface Sci. 2006 Dec 28; [Epub ahead of print]

  • Synthesis of Potent Bicyclic Bisarylimidazole c-Jun N-Terminal Kinase Inhibitors by Catalytic C-H Bond Activation.
    J Am Chem Soc. 2007 Jan 24;129(3):490-1.

  • Hydrogen-Atom Transfer in Open-Shell Organometallic Chemistry: The Reactivity of Rh(II)(cod) and Ir(II)(cod) Radicals.
    Chemistry. 2007 Jan 12; [Epub ahead of print]

  • Rhodium(I)-Catalyzed Allenic Carbocyclization Reaction Affording delta- and epsilon-Lactams.
    Org Lett. 2007 Jan 18;9(2):347-9.

  • Separation preconcentration method for platinum and rhodium from environmental samples using a chelating resin.
    Ann Chim. 2006 Nov-Dec;96(11-12):707-14.

  • Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds.
    Dalton Trans. 2007 Jan 28;(4):407-9. Epub 2006 Dec 13.

 

 

 

 

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